Organic electroluminescent materials and devices

    公开(公告)号:US11271177B2

    公开(公告)日:2022-03-08

    申请号:US16229215

    申请日:2018-12-21

    Abstract: A compound comprising a ligand LA coordinated to a metal M, the ligand LA selected from the group consisting of Formula I, Formula II, and Formula III ring A is a 5- or 6-membered carbocyclic or heterocyclic ring; wherein ring A of Formula I connects to ring B at X1, X2, or X3 to form a five-membered chelate ring with the metal; Z1 and Z2 are independently selected from C or N; and X1 to X10 are independently selected from C or N. An organic light emitting device (OLED) comprising an anode, a cathode and an organic layer disposed between the anode and the cathode, the organic layer comprising a compound selected from Formula I, Formula II, or Formula III, and a consumer product comprising the OLED.

    Organic electroluminescent materials and devices

    公开(公告)号:US11108000B2

    公开(公告)日:2021-08-31

    申请号:US15970244

    申请日:2018-05-03

    Abstract: A compound having the formula Ir(LA)n(LB)3−n is disclosed wherein LA is an aza-DBF ligand and LB is an alkyl-substituted phenylpyridine ligand, wherein the compound has a structure according to Formula I: wherein A1, A2, A3, A4, A5, A6, A7, and A8 comprise carbon or nitrogen; wherein at least one of A1, A2, A3, A4, A5, A6, A7, and A8 is nitrogen; wherein ring B is bonded to ring A through a C—C bond; wherein the iridium is bonded to ring A through a Ir—C bond; wherein X is O, S, or Se; wherein R1 and R2 each independently represent mono-, di-, tri-, tetra-substitution, or no substitution; wherein R′ and R″ each independently represent mono-, di-substitution, or no substitution; wherein any adjacent substitutions in R′, R″, R1, R2, R3, R4, R5, and R6 are optionally linked together to form a ring; wherein R1, R2, R′, and R″ are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein R3, R4, R5, and R6 are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, and combinations thereof; wherein n is an integer from 1 to 3; and wherein total number of carbons in at least one of the pairs R3 and R4, and R5 and R6 is at least four.

    Electroluminescent (2-phenylpyridine)iridium complexes and devices

    公开(公告)号:US10411200B2

    公开(公告)日:2019-09-10

    申请号:US14796213

    申请日:2015-07-10

    Abstract: A compound having the formula Ir(LA)n(LB)3-n is disclosed wherein LA is an aza-DBF ligand and LB is an alkyl-substituted phenylpyridine ligand, wherein the compound has a structure according to Formula I: wherein A1, A2, A3, A4, A5, A6, A7, and A8 comprise carbon or nitrogen; wherein at least one of A1, A2, A3, A4, A5, A6, A7, and A8 is nitrogen; wherein ring B is bonded to ring A through a C—C bond; wherein the iridium is bonded to ring A through a Ir—C bond; wherein X is O, S, or Se; wherein R1 and R2 each independently represent mono-, di-, tri-, tetra-substitution, or no substitution; wherein R′ and R″ each independently represent mono-, di-substitution, or no substitution; wherein any adjacent substitutions in R′, R″, R1, R2, R3, R4, R5, and R6 are optionally linked together to form a ring; wherein R1, R2, R′, and R″ are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein R3, R4, R5, and R6 are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, and combinations thereof; wherein n is an integer from 1 to 3; and wherein total number of carbons in at least one of the pairs R3 and R4, and R5 and R6 is at least four.

    Organic electroluminescent materials and devices

    公开(公告)号:US10400163B2

    公开(公告)日:2019-09-03

    申请号:US13762612

    申请日:2013-02-08

    Abstract: A compound according to Formula I and devices incorporating the same are described. The compound according to Formula I can have the structure wherein R2 represents mono, di, tri, tetra, penta substitutions or no substitution; R3, R4 and R5 each represent mono, di, tri, tetra substitutions or no substitution; wherein R9 represents mono, di, tri substitutions or no substitution; wherein R1 is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and R2, R3, R4 R5 and R9 are each independently selected from the group consisting of all options for R1, hydrogen, deuterium, halide, amino, silyl, and combinations thereof; and wherein n is 1 or 2. The device can include the compound according to Formula I in an organic layer.

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