The present disclosure provides a fiber-forming process that includes: providing a centrifugal electrospinning apparatus that includes: an emitter that includes a rotating element having a rotational speed of 10,000 rpm or less; and a collector; and providing a spinning solution including at least one polymer dissolved in at least one solvent; supplying the spinning solution to the emitter; and directing the spinning solution from the emitter toward the collector under conditions effective to form separate fibrous streams from the spinning solution, vaporize the solvent, and produce polymeric fibers on the collector.