A method and related system for linearizing a photonic ADC sampling system of an ELINT receiver includes modulating optical pulse trains of varied pulse amplitudes based on a generated ramped-voltage calibration signal. The modulated pulse trains are demodulated into I/Q components to generate signal constellations. Equivoltage radials are defined by points of the signal constellations sharing a common calibration voltage and a common phase angle of the modulator. A lookup table is generated by mapping the signal constellations and equivoltage radials to a coordinate system to determine, for each coordinate bin, a corresponding pulse amplitude and phase angle. The generated lookup table may be used to correct nonlinear distortions in recovered output signals, preserving high-ENOB performance and increasing the dynamic range of the receiver.