Invention Grant
- Patent Title: Mononuclear ruthenium complex and organic synthesis reaction using same
-
Application No.: US15124773Application Date: 2015-03-03
-
Publication No.: US09884316B2Publication Date: 2018-02-06
- Inventor: Hideo Nagashima , Yusuke Sunada , Hajime Ogushi , Koji Sakuta
- Applicant: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION , SHIN-ETSU CHEMICAL CO., LTD.
- Applicant Address: JP Fukuoka-shi JP Tokyo
- Assignee: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION,SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION,SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee Address: JP Fukuoka-shi JP Tokyo
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP2014-046121 20140310
- International Application: PCT/JP2015/056200 WO 20150303
- International Announcement: WO2015/137194 WO 20150917
- Main IPC: C07C69/38
- IPC: C07C69/38 ; B01J31/16 ; C07C209/50 ; C07F15/00 ; C07F19/00 ; C07C5/03 ; C07C67/303 ; C07C67/283 ; C07C209/62 ; C07F7/08

Abstract:
A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. (In the formula, R1-R6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R1-R3 and any of R4-R6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)
Public/Granted literature
- US20170056872A1 MONONUCLEAR RUTHENIUM COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME Public/Granted day:2017-03-02
Information query