A method, a recording medium and an electronic device of 3D geolocation are provided. The method includes the following steps: distributing a plurality of samples that are already 2D-geolocated into a plurality of geographic areas according to 2D locations of the samples, wherein each sample includes a measurement report provided by a user equipment attached to a mobile network; generating a relative sequence of altitudes of the samples in each geographic area according to altitude-related data obtained from the samples in the geographic area; and determining the altitudes of the samples in each geographic area according to the relative sequence of the geographic area.