Lithium ion devices that include an anode, a cathode and an electrolyte are provided. The anode having an active material including germanium nano-particles, boron carbide nano-particles and tungsten carbide nano-particles, wherein the weight percentage of the germanium is between 5 to 80 weight % of the total weight of the anode material, the weight percentage of boron in the anode material is between 2 to 20 weight % of the total weight of the anode material and the weight percentage of tungsten in the anode material is between 5 to 20 weight % of the total weight of the anode materials.