A liquid crystal panel includes a first substrate and a second substrate opposite to the first substrate, a liquid crystal layer interposed between the first substrate and the second substrate, and an enclosure resin frame located between the first substrate and the second substrate to enclose and seal the liquid crystal layer. The enclosure resin frame surrounds the liquid crystal layer that is located in a displaying zone of the liquid crystal panel. The enclosure resin frame includes spherical supports arranged therein. The spherical supports include an inner layer and an outer layer. At least one of the outer layer and the inner layer is made of a heat-shrinkable material, or alternatively, the inner layer and the outer layer are both made of heat-shrinkable materials. Also provided are a manufacturing method of a liquid crystal panel and a liquid crystal displaying device.