Invention Grant
US09590176B2 Controlling the conductivity of an oxide by applying voltage pulses to an ionic liquid 有权
通过向离子液体施加电压脉冲来控制氧化物的电导率

Controlling the conductivity of an oxide by applying voltage pulses to an ionic liquid
Abstract:
Electrolyte gating with ionic liquids is a powerful tool for inducing conducting phases in correlated insulators. An archetypal correlated material is VO2 which is insulating only at temperatures below a characteristic phase transition temperature. We show that electrolyte gating of epitaxial thin films of VO2 suppresses the metal-to-insulator transition and stabilizes the metallic phase to temperatures below 5 K even after the ionic liquid is completely removed. We provide compelling evidence that, rather than electrostatically induced carriers, electrolyte gating of VO2 leads to the electric field induced creation of oxygen vacancies, and the consequent migration of oxygen from the oxide film into the ionic liquid.
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