A novel Aromatic Thermosetting Copolyester (ATSP) can be processed into highly effective wear resistant coatings by blending with polytetrafluorethylene (PTFE) and other additives. Surface treatments/coatings are key to improving wear performance and durability in a wide array of applications. The problems associated with use of liquid lubricants, hard/soft coatings are well known but only modest progress has been achieved due to lack of research on new material systems. These coatings were fabricated and tested as highly effective wear resistant coatings by blending ATSP with PTFE and other tribologically beneficial additives. The main advantages of these polymeric-based coatings are their relatively low cost and simple substrate surface conditioning (i.e., no need for expensive surface preparation before coating).