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US09273169B2 Process for monomer recovery from a polymerization process 有权
从聚合过程中回收单体的方法

Process for monomer recovery from a polymerization process
Abstract:
The present relates to a process for optimizing the recovery of unreacted monomers from a polymerization process, wherein said process comprises the steps of recovering a fluid stream generated by the separation of the polyolefin product from the polymerization fluid comprising unreacted monomers and optionally comonomers; contacting said fluid stream in an absorption zone with a scrub liquid comprising at least one C4-10 hydrocarbons, thereby absorbing at least a portion of the unreacted monomers in said scrub liquid; and withdrawing from said absorption zone (i) a vapor overhead comprising light gas and (ii) an absorber bottoms scrub liquid comprising said C4-10 hydrocarbons and said unreacted monomer; thereby recovering said unreacted monomer in said absorber bottoms scrub liquid comprising said C4-10 hydrocarbons. The present invention also concerns a process for the recovery of unreacted monomers from a gas phase or slurry polymerization process, and also concerns a process for the production of polyolefins.
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