Invention Grant
- Patent Title: Halogen-free resin composition and method for fabricating halogen-free copper clad laminate using the same
- Patent Title (中): 无卤素树脂组合物及其制造方法
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Application No.: US13997542Application Date: 2011-09-03
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Publication No.: US09076573B2Publication Date: 2015-07-07
- Inventor: Yueshan He , Shiguo Su
- Applicant: Yueshan He , Shiguo Su
- Applicant Address: CN Guangdong
- Assignee: Guangdong Shengyi Sci. Tech Co., Ltd.
- Current Assignee: Guangdong Shengyi Sci. Tech Co., Ltd.
- Current Assignee Address: CN Guangdong
- Agency: McDonald Hopkins LLC
- Priority: CN201010602780 20101223
- International Application: PCT/CN2011/079308 WO 20110903
- International Announcement: WO2012/083728 WO 20120628
- Main IPC: C08K5/07
- IPC: C08K5/07 ; H01B3/40 ; B32B5/02 ; B32B15/14 ; C08J5/24 ; H01B19/04

Abstract:
The present invention relate to a halogen-free resin composition and a method for fabricating a halogen-free copper clad laminate using the same. The halogen-free resin composition comprises the following components: reactive small molecular polyphenylene oxide with a number average molecular weight of 500-3000, a polybenzoxazine resin, a phosphorus-containing epoxy resin, a composite curing agent, a curing promoter, a filler, and a benzene or ketone solvent. The method for fabricating a halogen-free copper clad laminate comprises: Step 1: dissolving reactive small molecular polyphenylene oxide with a number average molecular weight of 500-3000 in a benzene or ketone solvent, adding a polybenzoxazine resin after dissolution, and mixing by stirring, to prepare a solution for use; Step 2: adding a phosphorus-containing epoxy resin, a composite curing agent, a curing promoter, and a filler to the solution for use, and stirring uniformly, to obtain a colloidal solution; Step 3: evenly coating the prepared colloidal solution to E-glass cloth with an even surface and baking, to produce a B-stage partially cured prepreg; and Step 4: cutting the B-stage partially cured prepreg into a suitable size according to the size of a compressor, precisely overlaying, placing a copper foil on and under the laminated B-stage partially cured Prepregs, and pressing in a vacuum hot pressing machine, to obtain a halogen-free copper clad laminate.
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