The present disclosure discloses an organosilicon polymer, a solid electrolyte comprising the organosilicon polymer, and a corresponding solid-state lithium-ion battery. The organosilicon polymer of the present disclosure is a polymer compound comprising both an inorganic backbone-chain structure and an organic side-chain structure, and has the characteristics of both the organic polymer and the inorganic polymer as well as many unique properties. Therefore, the solid electrolyte formed by the organosilicon polymer and the solid-state lithium-ion battery thereof have many good characteristics including a good lithium-ion-conduction capability, better resistance to high temperatures, a wider range of operating temperatures, and better thermal stability.