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US08829217B2 Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods 有权
形成单源前体的方法，形成聚合物单源前体的方法和通过这些方法形成的单源前体

Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods
Abstract:
Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula ½{L2N(μ-X)2M′X2}2, and reacting MER with the intermediate products to form SSPs of the formula L2N(μ-ER)2M′(ER)2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M′ is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE1R1E1H and MER with one or more substances having the empirical formula L2N(μ-ER)2M′(ER)2 or L2N(μ-X)2M′(X)2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.
Abstract(Chinese):

形成单源前体（SSPs）的方法包括形成具有经验式½{L2N（μ-X）2M'X2} 2的中间产物，并使MER与中间产物反应形成式L2N（μ-ER）的SSP， 2M'（ER）2，其中L是路易斯碱，M是IA族原子，N是IB族原子，M'是IIIB原子，每个E是VIB族原子，每个X是VIIA族 原子或硝酸根，每个R基团是烷基，芳基，乙烯基，（全）氟烷基，（全）氟芳基，硅烷或氨基甲酰基。 形成聚合物或共聚物SSP的方法包括使HE1R1E1H和MER中的至少一种与一种或多种具有经验式L2N（μ-ER）2M'（ER）2或L2N（μ-X）2M'（X）2 以形成聚合物或共聚物SSP。 通过这种方法形成新的SSP和中间产品。

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