A sampling device has a valve body that comprises an inlet for connecting to an unloading pipe of a container containing dry bulk product, the inlet being shaped to receive a flow of dry bulk product from the container. The valve body has a first outlet which, when opened, discharges the dry bulk product that enters the valve body through the inlet. The valve body also has a second outlet which, when opened, discharges a sample of the dry bulk product, the second outlet having a cross-sectional area that is smaller than a cross-sectional area of the first outlet. The sampling device enables a sample of dry bulk product, e.g. cement, slag, fly ash, cement kiln dust, silica fume, silica sand, lime, alumina, flour, or any other similar dry powdery substance to be obtained safely from a transport container or vessel.