An I/Q demodulation apparatus and method with phase scanning are provided. The demodulation apparatus includes a ring oscillator, a first latch unit, a decoding unit, a counter unit, a second latch unit, a first arithmetical unit and a second arithmetical unit. The first latch unit samples phase signals outputted from the ring oscillator. The decoding unit decodes the output of the first latch unit to correspondingly generate fine code of a first, a second, a third and a fourth codes. The counter unit counts the phase signals. The second latch unit samples the output of the counter unit to correspondingly generate coarse code of the first, the second, the third and the fourth codes. The first arithmetical unit performs an addition/subtraction operation by using the first code and the second code. The second arithmetical unit performs the addition/subtraction operation by using the third code and the fourth code.