Invention Grant
US08663857B2 Process for the production of hydrogen by catalyzed hydrolysis of a complex hydride, and facility with semi continuous reactor for carrying out the method
失效
通过复合氢化物的催化水解生产氢气的方法,以及用于实施该方法的半连续反应器的设备
- Patent Title: Process for the production of hydrogen by catalyzed hydrolysis of a complex hydride, and facility with semi continuous reactor for carrying out the method
- Patent Title (中): 通过复合氢化物的催化水解生产氢气的方法,以及用于实施该方法的半连续反应器的设备
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Application No.: US13268095Application Date: 2011-10-07
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Publication No.: US08663857B2Publication Date: 2014-03-04
- Inventor: María de los Ángeles Jiménez Domínguez , María del Mar Jiménez Vega , Belén Sarmiento Marrón , Asunción Fernández Camacho , Gisela Mariana Arzac De Calvo , Enrique Jiménez Roca
- Applicant: María de los Ángeles Jiménez Domínguez , María del Mar Jiménez Vega , Belén Sarmiento Marrón , Asunción Fernández Camacho , Gisela Mariana Arzac De Calvo , Enrique Jiménez Roca
- Applicant Address: ES Sevilla
- Assignee: Abengoa Hidrogeno, S.A.
- Current Assignee: Abengoa Hidrogeno, S.A.
- Current Assignee Address: ES Sevilla
- Agency: Wenderoth, Lind & Ponack, L.L.P.
- Priority: ES201031899 20101221
- Main IPC: H01M8/06
- IPC: H01M8/06

Abstract:
The present invention relates to a process for producing a continuous flow of hydrogen by catalyzed hydrolysis of a complex hydride, which comprises at least adding continuously and at constant rate a fuel solution to a reactor comprising a complex hydride stabilized on a hydroxide on a cobalt boride catalyst that is added in excess inside said reactor. Sodium borohydride is preferably used, the hydroxide is sodium hydroxide and the catalyst is supported on nickel foam. Parameters and optimal conditions to achieve continuous production of hydrogen have been determined, which is essential in the operation of fuel cells. A facility comprising a semi continuous reactor designed to perform the above process, which needs no refrigeration is also an object of the present invention, as well as a washing and reactivation process of a catalyst of the type used in the process mentioned above.
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