Invention Grant
- Patent Title: Catalyst for preparing synthesis gas from natural gas and carbon dioxide, and preparation method thereof
- Patent Title (中): 由天然气和二氧化碳制备合成气的催化剂及其制备方法
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Application No.: US13055853Application Date: 2009-07-30
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Publication No.: US08524119B2Publication Date: 2013-09-03
- Inventor: Ki Won Jun , Seung-Chan Baek , Jong Wook Bae , Keh-Sik Min , Seok-Lyong Song , Tae-Young Oh
- Applicant: Ki Won Jun , Seung-Chan Baek , Jong Wook Bae , Keh-Sik Min , Seok-Lyong Song , Tae-Young Oh
- Applicant Address: KR Ulsan KR Daejeon
- Assignee: Hyundai Heavy Industries Co., Ltd.,Korea Research Institute of Chemical Technology
- Current Assignee: Hyundai Heavy Industries Co., Ltd.,Korea Research Institute of Chemical Technology
- Current Assignee Address: KR Ulsan KR Daejeon
- Agency: Dickstein Shapiro LLP
- Priority: KR1020080075787 20080801
- International Application: PCT/KR2009/004256 WO 20090730
- International Announcement: WO2010/013958 WO 20100204
- Main IPC: C01B3/26
- IPC: C01B3/26

Abstract:
Disclosed are a catalyst for preparing synthesis gas from natural gas and carbon dioxide, and a method for preparing the same. More particularly, a combined reforming process is performed as an economical way of using carbon dioxide, wherein steam reforming of natural gas is carried out simultaneously with carbon dioxide reforming of methane in such a manner that a predetermined ratio of carbon monoxide/carbon dioxide/hydrogen (H2/(2CO+3CO2)=0.85-1.15) is maintained. In this manner, the catalyst is used to prepare synthesis gas suitable for methanol synthesis and Fischer-Tropsch synthesis. Disclosed also is a method for preparing synthesis gas on a specific catalyst consisting of Ni/Ce/MgAlOx or Ni/Ce-Zr/MgAlOx. The catalyst is inhibited from deactivation caused by generation of cokes during the reaction as well as deactivation caused by reoxidation of nickel with water added during the reaction. Therefore, the catalyst shows excellent activity as compared to other catalysts for use in combined reforming.
Public/Granted literature
- US20110114892A1 CATALYST FOR PREPARING SYNTHESIS GAS FROM NATURAL GAS AND CARBON DIOXIDE, AND PREPARATION METHOD THEREOF Public/Granted day:2011-05-19
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