Invention Grant
- Patent Title: Offgas cleanup in olefin hydroformylation
- Patent Title (中): 烯烃加氢甲酰化中的废气净化
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Application No.: US13001930Application Date: 2009-08-19
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Publication No.: US08476476B2Publication Date: 2013-07-02
- Inventor: Eddy T. A. Van Driessche , Ronald D. Garton , Raphael F. Caers
- Applicant: Eddy T. A. Van Driessche , Ronald D. Garton , Raphael F. Caers
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Agent Leandro Arechederra, III
- Priority: EP08166548 20081014
- International Application: PCT/EP2009/005995 WO 20090819
- International Announcement: WO2010/022880 WO 20100304
- Main IPC: C07C45/50
- IPC: C07C45/50

Abstract:
In the hydroformylation of C5-C14 olefins with cobalt catalyst to produce C6-C15 oxygenates, where offgasses from the hydroformylation or cobalt removal step contain volatile cobalt compounds, the cobalt compounds are recovered by scrubbing the offgas with a liquid, and recycling the liquid to the cobalt removal step. Suitable scrubbing liquids are the organic cobalt-depleted hydroformylation reaction product or a downstream derivative thereof, or an aqueous solution of a Co2+ salt, preferably such salt of formic acid.
Public/Granted literature
- US20110184211A1 Offgas Cleanup in Olefin Hydroformylation Public/Granted day:2011-07-28
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