A photovoltaic (PV) system includes a fiber optical waveguide comprising an active core that hosts material configured to absorb and emit light, a cladding layer surrounding the active core, the cladding layer being configured to allow ambient light to pass through the cladding layer, and an exit port located proximate an end of the waveguide. The PV system further comprises one or more solar cells disposed at the exit port of the waveguide. The waveguide is configured to guide light to the one or more solar cells. Another photovoltaic (PV) system includes a waveguide comprising an active cladding layer hosting material configured to absorb and emit light, and a core layer configured to confine light emitted by the active cladding layer. The PV system further includes one or more solar cells disposed proximate the waveguide. The core layer is configured to guide light to the one or more solar cells.