Invention Grant
US08436112B2 Polyolefin production with a high performance support for a metallocene catalyst system
有权
聚烯烃生产具有高性能支持的茂金属催化剂体系
- Patent Title: Polyolefin production with a high performance support for a metallocene catalyst system
- Patent Title (中): 聚烯烃生产具有高性能支持的茂金属催化剂体系
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Application No.: US12013774Application Date: 2008-01-14
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Publication No.: US08436112B2Publication Date: 2013-05-07
- Inventor: Jun Tian , William Gauthier , David Rauscher , Shady Henry
- Applicant: Jun Tian , William Gauthier , David Rauscher , Shady Henry
- Applicant Address: US TX Houston
- Assignee: Fina Technology, Inc.
- Current Assignee: Fina Technology, Inc.
- Current Assignee Address: US TX Houston
- Main IPC: C08F4/52
- IPC: C08F4/52 ; C08F4/64 ; C08F4/76

Abstract:
The invention is directed to a metallocene catalyst system comprising an inert silica support having pores with a peak pore volume of greater than about 0.115 mL/g at a pore diameter between about 250 Angstroms and about 350 Angstroms, and an alumoxane activator, with the metallocene being bound substantially throughout the support. The activator is grafted to the support in a solvent at a reflux temperature of toluene to obtain an aluminoxane on silica, and a metallocene component is added to make a MCS having a metallocene loading of about 2 wt %. This facilitates the production of metallocene catalyst systems having increased catalytic activity than previously recognized that is at least about 20 percent higher than the catalytic activity for a metallocene loading of about 1 wt % where the activator is grafted to the support at room temperature.
Public/Granted literature
- US20080194399A1 Polyolefin Production with a High Performance Support for a Metallocene Catalyst System Public/Granted day:2008-08-14
Information query
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