Aminoplast-polythiol compositions resulting from the contact product, or cured reaction product, of an aminoplast resin composition and a polythiol composition are disclosed. Typically, the polythiol composition contains thiol ester molecules having an average of two or more thiol groups per molecule. Methods for preparing the aminoplast-polythiol compositions, methods for using the aminoplast-polythiol compositions to produce coatings and to coat substrates, and coatings and other articles produced using these aminoplast-polythiol compositions also are described.