Invention Grant
- Patent Title: Electrochemical capacitor containing ruthenium oxide electrodes
- Patent Title (中): 含有氧化钌电极的电化学电容器
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Application No.: US12331818Application Date: 2008-12-10
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Publication No.: US08385052B2Publication Date: 2013-02-26
- Inventor: Jessica M. Smith , Lee Shinaberger , Bob Knopsnyder , Gang Ning , Bharat Rawal , Dirk Dreissig
- Applicant: Jessica M. Smith , Lee Shinaberger , Bob Knopsnyder , Gang Ning , Bharat Rawal , Dirk Dreissig
- Applicant Address: US SC Myrtle Beach
- Assignee: AVX Corporation
- Current Assignee: AVX Corporation
- Current Assignee Address: US SC Myrtle Beach
- Agency: Dority & Manning, P.A.
- Main IPC: H01G9/00
- IPC: H01G9/00

Abstract:
A capacitor containing an electrochemical cell that includes ruthenium oxide electrodes and an aqueous electrolyte containing a polyprotic acid (e.g., sulfuric acid) is provided. More specifically, the electrodes each contain a substrate that is coated with a metal oxide film formed from a combination of ruthenium oxide and inorganic oxide particles (e.g., alumina, silica, etc.). Without intending to be limited by theory, it is believed that the inorganic oxide particles may enhance proton transfer (e.g., proton generation) in the aqueous electrolyte to form hydrated inorganic oxide complexes (e.g., [Al(H2O)63+] to [Al2(H2O)8(OH2)]4+). The inorganic oxide thus acts as a catalyst to both absorb and reversibly cleave water into protons and molecular bonded hydroxyl bridges. Because the anions (e.g., sulfate and bisulfate ions) in the electrolyte are not bound in the coordination sphere of the formed aqua complexes, they do not impede the condensation of these complexes required to achieve the additional capacitance over the potential range. As a result, the ionic charges are kept separate and the chemical process may generate pseudo-capacitance. This, in turn, may result in an increase in the charge density and capacitance of the electrode.
Public/Granted literature
- US20100142123A1 Electrochemical Capacitor Containing Ruthenium Oxide Electrodes Public/Granted day:2010-06-10
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