Invention Grant
- Patent Title: Metathesis catalyst and process for use thereof
- Patent Title (中): 复分解催化剂及其使用方法
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Application No.: US12705136Application Date: 2010-02-12
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Publication No.: US08237003B2Publication Date: 2012-08-07
- Inventor: Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
- Applicant: Matthew W. Holtcamp , Catherine Anne Faler , Caol P. Huff , Matthew S. Bedoya , John R. Hagadorn
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Main IPC: C07C6/04
- IPC: C07C6/04 ; C07C1/213 ; C07F15/00

Abstract:
This invention relates to a catalyst compound for the metathesis of olefins represented by the formula: wherein M is a Group 8 metal; X and X1 are anionic ligands; L is a neutral two electron donor; L1 is N, O, P, or S, preferably N or O; R is a C1 to C30 hydrocarbyl or a C1 to C30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; R1 is selected from the group consisting of hydrogen, a C1 to C30 hydrocarbyl, and a C1 to C30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C1 to C30 hydrocarbyls and C1 to C30 substituted hydrocarbyls. This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.
Public/Granted literature
- US20110112349A1 Metathesis Catalyst and Process for Use Thereof Public/Granted day:2011-05-12
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