This invention provides an ink composition capable of forming an image which has favorable curing sensitivity, is excellent in rubbing resistance and blocking properties, and has controlled surface stickiness and improved surface curing properties, an inkjet recording method using the ink composition, and a printed material; and the ink composition containing a polymer (a) including a partial structure selected from the group consisting of fluorine-substituted hydrocarbon group, a siloxane skeleton group, and a long-chain alkyl group; a radical polymerizable group, and a tertiary amine structure.