A mononuclear star-branched polymer dielectric material having a repeat unit of the formula (I): A-Bn   (I) wherein, A represents a multifunctional center having a functionality and a functional group with “n” arms; n is an integer greater than 2. B represents a hydrolyzed or partially hydrolyzed compound of the formula (II): wherein, X represents H or CH3; R represents H, alkyl or is selected from a group consisting of acetoxyl, t-butyl, t-butyldimethyl silyl, acid labile groups and acid stable groups; “a” is an integer from 1 to 5; y and z are molar ratio and are the numbers satisfying y+z=1, 0