Invention Grant
- Patent Title: Process for producing polybutadiene rubber and rubber composition
- Patent Title (中): 生产聚丁二烯橡胶和橡胶组合物的方法
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Application No.: US10596757Application Date: 2005-12-20
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Publication No.: US07884155B2Publication Date: 2011-02-08
- Inventor: Naomi Okamoto , Mitsuharu Anbe , Jyun Yamashita , Tetsuji Nakajima , Takashi Kitamura , Osamu Kimura , Takashi Wada
- Applicant: Naomi Okamoto , Mitsuharu Anbe , Jyun Yamashita , Tetsuji Nakajima , Takashi Kitamura , Osamu Kimura , Takashi Wada
- Applicant Address: JP Yamaguchi
- Assignee: Ube Industries, Ltd.
- Current Assignee: Ube Industries, Ltd.
- Current Assignee Address: JP Yamaguchi
- Agency: Panitch Schwarze Belisario & Nadel LLP
- Priority: JP2004-367702 20041220; JP2005-010687 20050118; JP2005-010688 20050118; JP2005-010689 20050118; JP2005-010690 20050118; JP2005-010691 20050118; JP2005-010692 20050118; JP2005-010693 20050118; JP2005-177170 20050617; JP2005-177171 20050617; JP2005-177172 20050617
- International Application: PCT/JP2005/023377 WO 20051220
- International Announcement: WO2006/054808 WO 20060526
- Main IPC: C08K3/34
- IPC: C08K3/34

Abstract:
A process for producing a vinyl-cis-polybutadiene rubber, including mixing (A) vinyl-cis-polybutadiene obtained by (1) a step of adding a cis-1,4-polymerization catalyst obtainable from an organoaluminum compound and a soluble cobalt compound to a mixture containing 1,3-butadiene and a hydrocarbon-based organic solvent as the major components and having an adjusted water content, thereby subjecting the 1,3-butadiene to cis-1,4-polymerization and subsequently, (2) a step of making a catalyst obtainable from a soluble cobalt compound, an organoaluminum compound represented by the general formula, AlR3 (wherein R represents an alkyl group having from 1 to 6 carbon atoms, a phenyl group, or a cycloalkyl group), and carbon disulfide present in the resulting polymerization reaction mixture, thereby subjecting the 1,3-butadiene to 1,2-polymerization; and (B) cis-polybutadiene obtained by a step of adding the foregoing cis-1,4-polymerization catalyst, thereby subjecting the 1,3-butadiene to cis-1,4-polymerization and a rubber composition containing the resulting rubber.
Public/Granted literature
- US20070197714A1 Process for producing polybutadiene rubber and rubber composition Public/Granted day:2007-08-23
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