Invention Grant
- Patent Title: Low corrosion in zeolite oligomerisation
- Patent Title (中): 沸石低聚中的低腐蚀性
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Application No.: US11914643Application Date: 2006-06-16
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Publication No.: US07880046B2Publication Date: 2011-02-01
- Inventor: John S. Godsmark , Georges M. K. Mathys , Hubertus J. Beckers , Raphael F. Caers , Roger Eijkhoudt , Stephen H. Brown
- Applicant: John S. Godsmark , Georges M. K. Mathys , Hubertus J. Beckers , Raphael F. Caers , Roger Eijkhoudt , Stephen H. Brown
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Agent Andrew B. Griffis; Leandro Arechederra
- Priority: GB0512377.3 20050617
- International Application: PCT/EP2006/005852 WO 20060616
- International Announcement: WO2006/133967 WO 20061221
- Main IPC: C07C2/02
- IPC: C07C2/02

Abstract:
Water reacts on molecular sieve catalysts used in oligomerization reactions and forms oxygenated compounds, in particular organic acids that may cause corrosion problems downstream of the reactor, in particular in distillation tower overhead systems and downstream thereof. A lowering of the presence of water in the feed prior to contacting thereof with the molecular sieve brings a significant reduction in corrosion downstream. At the same time, it has a significant beneficial effect on catalyst activity and brings a significant extension of catalyst life. Lowering water in the feed is particularly effective when organic nitrogen-containing Lewis bases are present in the feed, even at low levels.
Public/Granted literature
- US20080312484A1 Low Corrosion In Zeolite Oligomerisation Public/Granted day:2008-12-18
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