A method and apparatus for converting organic waste feed streams into usable liquid fuels by adjusting the ratio of carbon dioxide, carbon monoxide, and hydrogen in the effluent gas of a high temperature waste treatment system. A pressure swing adsorption (PSA) unit is used to remove carbon dioxide from the effluent gas of a high temperature waste treatment system, while leaving carbon monoxide and hydrogen, thereby producing a gas stream amenable to the production of methanol and other liquid fuels using commercially available catalytic reactors.