An intrinsic polarizer, including a sheet of PVA-type matrix that includes vinylene polymer blocks, the sheet defining a pass polarization axis and a block polarization axis perpendicular to the pass polarization axis, light having an electrical vector parallel to the pass polarization axis being substantially transmitted through the sheet and light having an electrical vector parallel to the block polarization axis being substantially absorbed by the vinylene blocks, the sheet exhibiting a dichroic ratio of more than 100.