A negative electrode active material with high capacity and excellent cycle performance and rate performance is provided. In addition, a secondary battery including the negative electrode active material, and an electronic device including the secondary battery are provided. Nanosilicon is mixed with a solid electrolyte containing lithium, titanium, phosphorus, and oxygen, and graphene oxide is further added thereto. Then, graphene oxide contained in the mixture is reduced with ethanol in which ascorbic acid and lithium hydroxide hydrate are dissolved, so that the negative electrode active material is manufactured.