Disclosed are an electrode having a three-dimensional structure, the electrode including: a porous nonwoven web including a plurality of polymer fibers that form an interconnected porous network; an active material composite positioned among the polymer fibers and including active material particles and a first conductive material; and a second conductive material positioned on an outer surface of the active material composite, wherein the interconnected porous network is filled homogeneously with the active material composite and the second conductive material to form a super lattice structure, and an electrochemical device including the electrode having a three-dimensional structure.