A positive electrode active material for a non-aqueous electrolyte secondary battery includes a lithium metal composite oxide, wherein the lithium metal composite oxide is represented by a general formula: LiaNi1-x-y-zCoxDyEzO2 (wherein, in the formula, 0.05≤x≤0.35, 0≤y≤0.35, 0.002≤z≤0.05, 1.00≤a≤1.30, an element D is at least one type of element selected from Mn, V, Mo, Nb, Ti, and W, and an element E is an element forming an alloy with lithium at a potential more noble than a potential in which ions of the element E are reduced), wherein the lithium metal composite oxide includes primary and secondary particles formed by aggregating the primary particles, wherein an oxide containing the element E exists at a surface of at least either of the primary and secondary particles.