Diffractive optical structures, lenses, waveplates, devices, systems and methods, which have the same effect on light regardless of temperature within an operating temperature range. Temperature-compensated switchable diffractive waveplate systems, in which the diffraction efficiency can be maximized for the operating wavelength and temperature by means of adjustment of the electric potential across the liquid crystal or other anisotropic material in the diffracting state of the diffractive state, based on prior measurements of diffraction efficiency as a function of wavelength and temperature. The switchable diffractive waveplates can be a switchable diffractive waveplate diffuser, a switchable cycloidal diffractive waveplate, and a switchable diffractive waveplate lens. An electronic controller can apply an electric potential to the switchable diffractive waveplate. Amplitudes of the electric potential can be determined from lookup tables such that diffraction efficiency at an operating wavelength and measured temperature is maximized. A communications channel can transfer the measured temperature from temperature measurement means to the electronic controller.