The present disclosure is directed to a process for the preparation of resin-inorganic fibers composite and the obtained resin-inorganic fibers composite for coating. The process comprises the step of providing inorganic fibers bearing one or more monomer functional groups reactive with a monomer component; and reacting resin-forming monomer components with the inorganic fibers bearing one or more monomer functional groups reactive with a monomer component, to obtain the resin-inorganic fibers composite, wherein the resin is selected from the group consisting of alkyd resin, polyester resin and a combination thereof. The present disclosure is also directed to a coating composition containing the composite and a coating formed from the coating composition.