A method and an electronic device for executing data reading/writing in volume migration are provided. The method includes: preventing a read/write action on a first volume; switching an execution object of the read/write action to a brand new second volume; releasing the read/write action so that the read/write action is executed on the second volume; and migrating data in the first volume to the second volume, and during migration, if the second volume already has data, skipping migrating content at a corresponding address in the first volume to the second volume.