A method and device for calibrating an RC oscillator, a storage medium and a processor are provided. The method may include: in a first communication time period, a frequency of a first RC oscillator is adjusted at a first communication frequency point; at the first communication frequency point, the frequency of the first RC oscillator is adjusted according to a default gear of the first RC oscillator sequentially, and at least one of a corresponding gear value and a corresponding frequency when the first device end may receive or may not receive data sent by a second device end is recorded; a first target frequency and a first target gear value of the first RC oscillator are determined according to the at least one of a corresponding gear value and a corresponding frequency; and the first device end is controlled to communicate with the second device end at a second communication frequency point which is determined by the first target gear value in a second communication time period.