Organic or hybrid electronic device, having an NIP structure, such as an organic light-emitting diode, an organic photodetector, or an organic photovoltaic cell, comprising successively: a transparent substrate, a first transparent and electrically conducting electrode, an N type layer, an active layer comprising a polyethylenimine and: an electron donor material and an electron acceptor material, or a perovskite material, a P type layer, and a second electrode.