A solid-state polymer lithium battery pack and a preparation method therefor are provided. The lithium battery pack includes: single batteries (1), connecting sleeve members (2), electric cables (3), a battery box (4) and a pouring sealant, and has functions of power supply, power storage and multiple charging/discharging. The preparation method includes: connecting a plurality of single batteries in series by means of connecting sleeve members (2) to form combined batteries; connecting a plurality of combined batteries in series to form a lithium battery pack; and finally, assembling the lithium battery pack into a battery box (4), filling a pouring sealant inside the battery box by means of a sealant pouring process for fixing the single batteries (1) and internal electric cables (3), and discharging air in the battery box (4), so that a final solid-state polymer lithium battery pack is obtained.