Disclosed are a photovoltaic air-conditioning system and a photovoltaic air conditioner having same. The photovoltaic air-conditioning system comprises a photovoltaic battery, a switch module, an inverter circuit, a rectification circuit and a compressor inverter; an input end of the switch module is electrically connected to a power grid; a first output end of the switch module is electrically connected to a first input/output end of the inverter circuit; a second output end of the switch module is electrically connected to an input end of the rectification circuit; an output end of the rectification circuit is electrically connected to an input end of the compressor inverter; the input end of the switch module is not simultaneously conducting with both of the first output end and the second output end of the switch module.