Electro-optic assemblies and related materials (e.g., adhesive) tier use therein are generally provided. The adhesive layer may comprise an end-capped polyurethane. Some adhesive layers comprise two or more reactive functional groups (e.g., reactive functional groups configured to react with one or more curing species such that, for example, at least one of the two or more functional groups forms a crosslink). The adhesive may also comprise a chain-extending reagent that includes one or more reactive functional groups. In some embodiments, the adhesive is cured by reacting one or more reactive functional groups with one or more curing species. Curing the adhesive may comprise two or more curing steps. In some embodiments the adhesive layer may comprise one or more cross-linkers.