An article of self-light-emitting clothing includes an article of clothing, a driver device and a group of electric coupling switches. The article of clothing includes a light-emitting component, and first and second arrangement areas, and when the article of clothing is folded, the first and second arrangement areas can contact each other; otherwise, the first and second arrangement areas are separated. The driver device includes a battery and a switch circuit. The group of electric coupling switches includes first and second couplers disposed on the first and second arrangement area, respectively. When the first coupler and the second coupler are electrically coupled to each other, the switch circuit is in open-circuit status to disconnect the battery and the light-emitting component. When the first coupler is not electrically coupled to the second coupler, the switch circuit is conducted to enable the battery to supply power to the light-emitting component.