The honeycomb structure includes a pillar-shaped honeycomb structure body, and a circumferential coating layer disposed to surround a circumference of the honeycomb structure body, and cells which are formed at an outermost circumference of the honeycomb structure body and in which peripheries of the cells are defined by the partition walls without any lacks are defined as outermost circumference complete cells, and in a cross section of the honeycomb structure body which is perpendicular to an extending direction of the cells a minimum distance T (mm) among distances from the outermost circumference complete cells to the surface of the circumferential coating layer and a porosity P (%) of the circumferential coating layer satisfy relations of Equation (1) and Equation (2) as follows: 1.5≥T≥16×(100−P)−1.4; and  Equation (1): 20≤P≤75  Equation (2).