Energy storage devices are disclosed that store both electrical and mechanical energies, making the total energy stored larger than either an electrical or mechanical means alone. The energy storage device is charged by the application of a voltage, which charges a capacitor to store electrical energy while simultaneously exerting a force on the mechanical system that deforms the mechanical system, resulting in mechanical energy storage. When the charged device is discharged, both the electrical and mechanical energy are extracted in electrical form. Its unique features include, but are not limited to, the potential for long lifetime, improved safety, better portability, a wide operating temperature range, and environment friendliness. Arrays of energy storage devices can be assembled in various configurations to build high capacity energy storage units.