A structure of a combustion chamber is provided. The structure includes a cavity formed in a central part of a crown surface of a piston and a wall surface constituting the cavity. The wall surface has a central ridge portion bulging farther toward a bottom surface of a cylinder head toward a center of the cavity, a periphery concave portion formed radially outward of the central ridge portion to concave radially outward, and a lip portion formed between the periphery concave portion and an opening edge of the cavity to convex radially inward. An outer circumferential part of the crown surface has a first portion and a second portion located radially outward of the first portion. A stepped portion is formed between the first and second portions. A stepped portion volume ratio of a stepped portion volume to a top dead center volume is set to 0.1 or smaller.