A medical headgear fabric that includes, at least: (i) a skin-facing fabric layer; (ii) an outermost fabric layer; and (iii) a plastic or metal layer located between the fabric layers. Preferably these layers, as well as any additional layers that may be present in the fabric are thermoformed to form a substantially unitary fabric with at least a substantially laminate structure. Preferably, the fabric also includes a foam layer located between the fabric layers. Preferably, in embodiments with a layer (iii) of plastic, the plastic layer is in the form of a nylon, plastic strip. Preferably, in embodiments with a layer (iii) of metal, the metal layer is in the form of an aluminum strip.