The invention discloses a method used for leaching antimony and manganese simultaneously from stibnite and pyrolusite. The method comprises the steps that (1) the stibnite and pyrolusite are disposedin hydrochloric acid solutions to be leached simultaneously, and then liquid-solid separation is conducted on leached ore pulp to obtain leaching liquid I containing antimony manganese salt solutionsand sulfur-containing leaching residue; (2) antimony powder is added to the leaching liquid I for restoring to obtain leaching liquid II with antimony butter and manganese chloride as priority; and (3) the leaching liquid II is hydrolyzed, and antimony oxychloride hydrolysis residue and manganese chloride solutions can be obtained after liquid-solid separation. A wet process is adopted to leach the antimony and the manganese simultaneously from the stibnite and the pyrolusite, and poor production environment, serious sulfur dioxide pollution and other problems in the pyrometallurgy process areeffectively avoided. The method is suitable for low-grade stibnite and low-grade pyrolusite to improve the utilization rate of increasingly depleted antimony ore and manganese ore resources and reduce environmental pollution.