The invention discloses a production method for titanium brown with high near-infrared reflectivity. The method comprises the following steps: based on high reaction activity of nano-scale hydrous titanium dioxide, selecting suitable nano-scale hydrous titanium dioxide, adding additives, such as, n-titanic acid sol, zinc element, antimony oxide, phosphoric acid and chromic oxide, calcining under high temperature, crushing and removing salt, thereby acquiring the titanium brown with high near-infrared reflectivity. The product has obvious characteristics of reasonable size distribution, moderate color, easiness in dispersing and high near-infrared reflectivity and is an ideal product for a brown near-infrared reflection functional material.