The invention describes a process for the production of 4-hydroxybutyraldehyde. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solventThe invention describes a process for the production of 4-hydroxybutyraldehyde. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solventand a catalyst system comprising a rhodium complex and a 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis[bis(3,5-di-n-alkylphenyl)phosphino]butane. The process gives high yield of 4-hydroxybutyraldehyde c and a catalyst system comprising a rhodium complex and a 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis[bis(3,5-di-n-alkylphenyl)phosphino]butane. The process gives high yield of 4-hydroxybutyraldehyde compared to 3-hydroxy-2-methylpropionaldehyde.ompared to 3-hydroxy-2-methylpropionaldehyde.